| Center |
| Faculty of Chemistry |
| Departament |
| Physical Chemistry |
| Lecturers in charge |
| G8238 - RAFAEL VIRUELA MARTIN |
| Met. Docent |
| Theory and practical classes |
| Met. Avaluació |
| - - |
| Bibliografia |
| Continguts |
| Theory program: Topic 1. Formal Chemical Kinetics. - Introduction. - Expression of the speed of chemical reactions. - The laws of speed. - The reaction mechanism. - Relationship between mechanism and the laws of speed: Balance hypothesis. Stationary state. - Factors that influence specific speeds. - The study of reactions that follow a certain order: First order reactions. Any order reactions. - The study of complex reactions: Serial reactions. Competitive reactions. The reactions of balance and first order. Topic 2. The thermodynamic study of systems of single components. - Introduction. - Phase and component concepts. . - Conditions of balance. material. - The rules of phases. - Behavior of chemical potential when subjected to pressure and temperature. - pressure-temperature diagrams. - The Calpeyron equation. . Topic 3. Non- electrolytic dissolutions (I). - Introduction. - Activity of dissolved components . - The activity coefficient. - Agreements, scales and reference states. - Partial molar properties. - Determination of molar magnitudes . - Thermodynamic properties of mixtures: Thermodynamic conditions of miscibility. - Thermodynamic properties of excess: Calculation starting from gE. Topic 4. Non-electrolytic dissolutions. (II). - Common properties . - The Gibbs-Duhem equation. - Margules equation. - Met |