| Center |
| Faculty of Biological Sciences |
| Departament |
| Physical Chemistry |
| Lecturers in charge |
| Sin datos cargados |
| Met. Docent |
| Theory and practical classes |
| Met. Avaluació |
| Final examination - - |
| Bibliografia |
| A.- Manuales de Química Física. 01.- Alberty, R.A. y Silbey, R.J., "Physycal Chemistry", Wiley, N. York, 1992. 02.- Atkins, P.W., "Fisicoquímica", 3ª Edición, Addison.Wesley Iberoamericana, Wilmington, 1991. 03.- Atkins, P.W., "Química Física", 6ª edición, Ediciones Omega, S.A., 1998. Trad. Al castellano por B.L÷eb Lüschow y M.A. Ríos Fernández. 04.- Barrow, G.M., "Química Física", 6ª Edición, Reverté, Barcelona, 1988, Traducción al castellano por S.Senent. 05.- Berry, R.S., Rice, A.S. y Ross, J., "Physical Chemistry", (3 vol.), Wiley, N.York, 1980. 06.- Castellán, G.W., "Fisicoquímica", Addison.Wesley Iberoamericana, Wilmington, 1990. Trad. Al castellano por M. Costas Basín y M.A. C. Amador Bedolla. |
| Continguts |
| Theory program: Topic 1. Formal Chemical Kinetics. - Introduction. - Expression of the speed of chemical reactions. - The laws of speed. - The reaction mechanism. - Relationship between mechanism and the laws of speed: Balance hypothesis. Stationary state. - Factors that influence specific speeds. - The study of reactions that follow a certain order: First order reactions. Any order reactions. - The study of complex reactions: Serial reactions. Competitive reactions. The reactions of balance and first order. Topic 2. The thermodynamic study of systems of single components. - Introduction. - Phase and component concepts. . - Conditions of balance. material. - The rules of phases. - Behavior of chemical potential when subjected to pressure and temperature. - pressure-temperature diagrams. - The Calpeyron equation. . Topic 3. Non- electrolytic dissolutions (I). - Introduction. - Activity of dissolved components . - The activity coefficient. - Agreements, scales and reference states. - Partial molar properties. - Determination of molar magnitudes . - Thermodynamic properties of mixtures: Thermodynamic conditions of miscibility. - Thermodynamic properties of excess: Calculation starting from gE. Topic 4. Non-electrolytic dissolutions. (II). - Common properties . - The Gibbs-Duhem equation. - Margules equation. - Met |