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12869 Molecular Spectroscopy - M. NANOSCIENCE AND NANOTECHNOLOGY

Center

Student Information Service-Master

Departament

Physical Chemistry

Lecturers in charge

Sin datos cargados

Met. Docent

Theory and practical classes

Met. Avaluació

Final examination - -

Bibliografia

¿ Textos de Química Física:

P.W. Atkins
"Fisicoquímica", 3ª ed. (trad. 3ª ed. inglesa, 1986), Addison-Wesley Iberoamericana, 1991.
"Physical Chemistry", 5ª ed. Oxford University Press, 1994.

I.N. Levine
"Fisicoquímica", 3ª ed. (trad. 3ª ed. inglesa), McGraw-Hill, 1991.
"Fisicoquímica", 4ª ed. (trad. 4ª ed. inglesa), McGraw-Hill, 1996.

R.A. Alberty y R.J. Silbey
"Physical Chemistry", John Wiley & Sons, 1992.

K.G. Vemulapalli
"Physical Chemistry", Prentice Hall, 1993.

M. Díaz Peña y A. Roig Muntaner
"Química Física", Alhambra, 1972, Vol. 1.

Textos de espectroscopia (nivel general)

C.N. Banwell y E.M. McCash
"Fundamentals of Molecular Spectroscopy", 4ª ed., McGraw-Hill, 1994.

G.M. Bar

Continguts

OBJECTIVES:

Basic presentation of molecular spectography and of magnetic resonance, it is expected that the students understand the reasons for the different useful spectographic phenomena of Physical Chemistry and learn how to extract quantitative structural information from it.

CONTENTS:

Topic 1. Foundations of Spectography
Electromagnetic radiation. Concepts of quantum mechanics. Regions of electromagnetic spectrum. Types of spectra. Einsteins probabilities of absorption and emission. Radiation-matter interaction. The moment of transition and rules of selection. The spectographic signs: position, intensity and width. Law of Lambert-Beer. Integrated coefficients of absorption. Laser emissions. Spectographics of Fourier.

Topic 2. Spectographics of Microwaves
Classic rotors: Tensile of inertia. Spectra of pure rotation of diatomic molecules . Spectra of pure rotation of politomic molecules. Experimental techniques. Stark effect . Hyperfine structures. .

Topic 3. Infrared Spectography.
Harmonic and inharmonic lineal oscillators. Spectral vibrations of diatromic molecules. Rotational structures : Spectra Rotation-vibration of diatomic molecules. Vibration of molecules poliatomic molecules, modes and coordinated norms. Quantum treatment of molecular vibration. Rotation-vibration in poliatomic molecules: Parallel and perpendicular bands. Interaction among vibrations.