Ficha técnica de una asignatura en una titulación

12863 Electrochemistry - Five-year degree in Chemistry

Center

Faculty of Chemistry

Departament

Physical Chemistry

Lecturers in charge

F3083 - FRANCISCO VICENTE PEDROS

Met. Docent

Theory and practical classes

Met. Avaluació

Final examination - -

Bibliografia

Antropov, L. "Theoretical Electrochemistry", Mir, Moscú, 1973.
Besson, J. "Process de thermodinamique et Cinetique electrochimiques", Ellipses, Paris, 1984

Bockris, J.O.M. y Reddy, A.K.N. "Electroquímica Moderna". (2 vol., trad. J. Beltrán), Reverté, Barcelona, 1978.
Crow, D.R. "Principles and Applications of Electrochemistry", (2 ed.), Halsted (Wiley), N.Y., 1979.
Damaskin, B.B. y Petri, O.A. "Fundamentos de la Electroquímica Teórica", Mir, Moscú, 1981.
Koryta, J., Dvorak, J. y Kavan, L. "Principles of Electrochemistry", Wiley, N.Y., 1993.
Pourbaix, M. "Lecciones de Corrosión Electroquímica", Madrid, 1987
Rieger, P.H. "Electrochemistry", Chapman &Hall, New York, London (1993).

Continguts

Content:

1. - General overview of the Electrochemistry
History. - Interdisciplinary characteristics of Electrochemistry. - Foundations of electrochemical laboratory techniques. - Cause of electrochemical irreversibility. - semi-empiric treatment of a reaction controlled by materials. - electrochemical Cells: Approaches to the signs and scales of power. - mathematical Methods.

2. - Transportation of loads.
Electric conduction. - Conductivity of solutions. - Diffusion of ions in dissolution. - Transport of material in electrochemical cells. - Nernst-Planck Equations - Indexes of transport. - Conductometrics.

3. - Electrochemistry of balance.
Electrochemical potential. - electrode Potential: Types of electrodes. - Origin of electrode potential. - Potenciometría. - Thermodynamics of a reversible battery. - Determination of the product of a soluable salt. - Determination of coefficients. - Measure of indexes of transport. - membrane Potential. - Henderson and Donnan Equations.

4. - the electrode dissolution interphase.
Potential of zero load. -models of the electrode/dissolutionm interphase.. - Isotherm of adsorption. - thermodynamic considerations of the adsorption of more than enough electrodes. - Frumkin methods and measures of capacity. - . - Curved electrocapiliaries. - Capacity curves. - Adsorption and its structures.

5. - electrochemical kinetics
Transfer of electrons. -